Odd Test Results

Discussion in 'Water Chemistry' started by blackraven1425, Sep 27, 2010.

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  1. blackraven1425

    blackraven1425 Giant Squid

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    Ok, so I got some new Salifert kits to replace the Red Sea ones I had before. The RS calcium was easy enough, but it was measured in increments of 50ppm, so I wanted something a bit more accurate. The alk was garbage.

    I tested the first night, got 8 dkh for alk, and 450 ppm calcium. I dosed alk, according to BRS's calculator, up to a desired result of 10 dkh.

    I tested 3 days later, and got results of 10.2dkh alk, and 420ppm calcium. I figured the alk was higher as a result of a low number for tank gallonage. So, I again dosed according to BRS's calculator, so that calcium would be up to 450ppm, using the same number of gallons.

    I then tested again tonight (3 more days), and got a result of 450ppm calcium, and 8.3 dkh. Is it just me, or are these numbers outright weird? I can't imagine my gallonage estimate being off by such an amount as to cause this discrepancy. It seems the tank's inhabitants are using a bunch of alk, then a bunch of calcium, and alternating like that.

    I say that I can't imagine my gallonage being off by this much, because in order to have 480 ppm calcium after dosing it, I would need to be that far off. It would need to be 480 ppm calcium, otherwise I wouldn't be getting a result of 450 3 days after dosing, while knowing my consumption is about 10 ppm per day from the first gap.

    :confused::confused::confused:
     
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  3. steve wright

    steve wright Super Moderator

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    They dont seem weird to me

    its the 20 - 1 ratio almost

    when you increased ALK by 2 - your calc dropped 30
    you increase Calk by 30 and your Alk drops by 2

    whats your Mag level - is it able to support your 2 target numbers?

    Steve
     
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  4. Corailline

    Corailline Super Moderator

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    Interesting

    Do you have values for your pH or mag ?

    If you mag value is low you may want to consider that as the cause for the fluctuating alk.
     
  5. blackraven1425

    blackraven1425 Giant Squid

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    My mag is about 1300. Is that too low to support my alk/cal values?
     
  6. Dingo

    Dingo Giant Squid

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    this doesnt seem out of place to me... seems about right.
    as alk is increased, ca decreases. the only way to make them both be high is to have a higher magnesium level. as you dose ca, your alk will always decrease, and as you dose alk, your ca will always decrease.

    trick i have found for keeping the ca stable (and then the alk will follow) is to shoot to have your mg at a very stable, non-fluctuating level roughly 3.1-3.5 times the level of your ca. this should cause everything to fall into place nicely. Then after a few days your ca will level out, and a few days later your alk will then follow.

    once your there, by monitoring alk closely you can then know if anything is going to change; a fluctuation in alk will mean a fluctuation in ca is to follow in a few days, and possibly a fluctuation in mg after that if its significant enough.
     
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  7. Dingo

    Dingo Giant Squid

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    from your first post I assume your shooting for ca 450ppm?
    if thats the case then i would take mg up to 1395ppm and see if things level off then :)
     
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  9. blackraven1425

    blackraven1425 Giant Squid

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    Yeah, I was aiming for 450 calcium and 10 dkh.

    For future reference, what's the formula for the maximum alk/cal combo?
     
  10. steve wright

    steve wright Super Moderator

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    Dingo said it all
    but yes 1300 does seem low to support those numbers
    I maintained 440 Calc and 9 DKH with a Mag level between 1410 and 1450

    Steve
     
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  11. Dingo

    Dingo Giant Squid

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    IME, alk is usually variable based on things like: type of dosing, oxygen in tank, ca reactor, kalk.

    But the [Mg] determines what the [Ca] is... Ca is usually (1/3.1) times Mg or put in easier terms, Ca x 3.1 = Mg.
    everything else is just equilibrium ;)
    Im sure you already know about it but re-read randy holmes-farley's article in reefkeeping magazine again Reef Aquarium Water Parameters by Randy Holmes-Farley - Reefkeeping.com
     
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  12. Reeron

    Reeron Blue Ringed Angel

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    I aim for dKH of 10-11, Calcium of 440-460 ppm and Magnesium of 1400-1450 ppm. I think your Magnesium is too low and you are chasing Calcium and Alkalinity. Adjust Mag first and no more than 100 ppm per day. I like a lesser rate increase so I shoot for 50 ppm per day. Then you can go after Alkalinity and Calcium.
     
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