Raising pH without changing dKh???

Discussion in 'ASAP' started by Zzippper, Dec 20, 2008.

to remove this notice and enjoy 3reef content with less ads. 3reef membership is free.

  1. Zzippper

    Zzippper Spanish Shawl Nudibranch

    Joined:
    Jul 17, 2008
    Messages:
    82
    Location:
    Ottawa, Ontario Canada
    What is the best way to raise pH without changing the dKh?

    Typically, when the pH of my tank drops - the dKh does too. I solve both by using Reef Buffer from Seachem.

    Trouble is... I've recently added a sulfur denitrator (which works awesome, by the way) and the denitrator effluent has a pH of 7.3. For some reason, it is lowering the tanks overall pH but not effecting the dkH.

    I've added more buffer - and it does raise the pH - but it also raises the dkH. I don't want to add anymore buffer because the dKh has gotten too high (currently 16).

    Advise? Anyone?

    Thanks!

    Z
     
  2. Click Here!

  3. lunatik_69

    lunatik_69 Giant Squid

    Joined:
    Jul 10, 2007
    Messages:
    7,933
    Location:
    Miami, FL

    Introduce fresh air to the tank. Either by opening a window(maybe not a good idea for you) or place an air pump outside and run the tubes into the tank with air stones. What was your ph before using the sulfur denitrator ? Luna
     
    1 person likes this.
  4. nanoreefer555

    nanoreefer555 Fire Shrimp

    Joined:
    Mar 23, 2008
    Messages:
    324
    Are you using a calcium reactor chamber to pass the effluent through? If not that is likely your prob.

    Check out this rather heady chemical explanation:

    Chemistry and the Aquarium

    Also there are some old threads on 3reef that go into this process in detail.
     
  5. Bogie

    Bogie Snowflake Eel

    Joined:
    Feb 7, 2008
    Messages:
    2,350
    Location:
    CT
    You might be able to raise just your pH by adding borate.
    How many gallons, and how much do you want to raise it?
     
  6. Zzippper

    Zzippper Spanish Shawl Nudibranch

    Joined:
    Jul 17, 2008
    Messages:
    82
    Location:
    Ottawa, Ontario Canada
    Thanks for the responses.

    pH before installing the sulfur denitrator was a very, very stable 8.1 - for months.

    The denitrator itself contains both sulfur and aragonite (commercial mix from Carib-sea called NO-NO3). Additionally, it is a re-circulation reactor:
    1. Small amount of tank water is pumped into the reactor
    2. Water in the reactor continously recirculates from bottom to top through the media and is then pumped back to the bottom of the unit to repeat the process. This maximizes exposure (contact time) with the media and increases the de-nitrification and acid-netralization efficiency dramatically.
    3. Small amount of water exits the reator (effluent).
    Despite the recirculation - the effluent still has a slightly lower pH. I have two ideas:

    1) Based on Luna's response - I am thinking of dripping the effluent into a 'pre-chamber' and adding an air stone to that chamber.

    3) What about adding Kalk to my top off water?


    Z
     
  7. Zzippper

    Zzippper Spanish Shawl Nudibranch

    Joined:
    Jul 17, 2008
    Messages:
    82
    Location:
    Ottawa, Ontario Canada
    This is a good question... 65g is the easy part.
    How much do I want to raise the pH is the tricky part as it depends on how much it has dropped from one day to the next. My goal is to maintain a consistent pH of 8.2.

    Does this help?

    Z
     
    Last edited: Dec 20, 2008
  8. Click Here!

  9. reef_guru

    reef_guru Humpback Whale

    Joined:
    Apr 4, 2007
    Messages:
    2,753
    Location:
    joliet,il
    Last edited: Dec 20, 2008
    1 person likes this.
  10. Zzippper

    Zzippper Spanish Shawl Nudibranch

    Joined:
    Jul 17, 2008
    Messages:
    82
    Location:
    Ottawa, Ontario Canada
    K+ to Luna for a great idea.

    I threw together an 'effluent aeration chamber' with an air-stone/air-pump and dripped the effluent into that before returning it to the sump.

    The effects were positive and immediate.
    pH of effluent directly from the denitrator = 7.3
    pH of aerated effluent = 8

    Thanks to all who responded!


    Z
     
  11. nanoreefer555

    nanoreefer555 Fire Shrimp

    Joined:
    Mar 23, 2008
    Messages:
    324
    I am wondering why the aragonite in the mixture did not buffer the way it should have. Anybody have any ideas? I thought the other benefit of the sulfur denitrator was its buffering capacity (provided that a calcium reactor is subsequent).

    It is sweet though when someone gives you such a quick easy fix (e.g. Luna).
     
  12. reef_guru

    reef_guru Humpback Whale

    Joined:
    Apr 4, 2007
    Messages:
    2,753
    Location:
    joliet,il
    on my tank the effluent goes into the skimmer using air from the outside with a pump. the skimmer is its own aeration chamber.